Standard Test Method for Moisture and Residue in Liquid Chlorine

1.1 This test method covers the determination of moisture and residue in liquid chlorine. Lower limits of detection of 10 ppm (w/w) based on a 150 mL sample are achievable.

1.2 This test method describes operations and special apparatus for sampling liquid chlorine from cylinders. Sampling other commercial facilities such as tank cars, barges, and storage tanks require special techniques of manipulation in filling sample cylinders for testing. If conditions and facilities are favorable, the analysis apparatus may be connected directly to these larger storage and transportation units and on-the-spot tests may be completed.

1.3 The analytical methods are empirical and are gravimetric. They are applicable to the determination of the residue and moisture content of commercial grades of liquid chlorine (condensed gaseous product).

1.4 Residue is defined as being those substances which remain in the sample flask after sample volatilization under the conditions of the test. Moisture is defined as the volatile substances evolved during volatilization and purging of the sample-residue flask and absorbed on the desiccant contained in the absorption tubes under the conditions of the test. Some of the volatile chlorinated hydrocarbons may also be evolved from the sample residue flask during purge and absorbed, thus contributing to the apparent moisture analysis value.

1.5 This test method may be used for determining the moisture content only of gaseous chlorine if suitable and appropriate modifications are made for sample measurement and calculation.

1.6 The values stated in inch-pound units are to be regarded as the standard. The metric equivalents of inch-pound units may be approximate.

1.7 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 7.