Standard Test Method for Gamma Alumina Content in Catalysts Containing Silica and Alumina by X-ray Powder Diffraction

This test method is for estimating the relative amount of gamma alumina in calcined catalyst samples, assuming that the X-ray powder diffraction peak occurring at about 67 °2θ is attributable to gamma alumina. Gamma alumina is defined as a transition alumina formed after heating in the range from 500 to 550°C, and may include forms described in the literature as eta, chi, and gamma aluminas. Delta alumina has a diffraction peak in the same region, but is formed above 850°C, a temperature to which most catalysts of this type are not heated. There are other possible components which may cause some interference, such as alpha-quartz and zeolite Y, as well as aluminum-containing spinels formed at elevated temperatures. If the presence of interfering material is suspected, the diffraction pattern should be examined in greater detail. More significant interference may be caused by the presence of large amounts of heavy metals or rare earths, which exhibit strong X-ray absorption and scattering. Comparisons between similar materials, therefore, may be more appropriate than those between widely varying materials.