Characteristics of Hydride Precipitation and Reorientation in Spent-Fuel Cladding
SourceTransmission electron microscopy (TEM) was used to examine Zircaloy fuel ladding, either discharged from several PWRs and a BWR after irradiation to fluence levels of 3.3 to 8.6 × 1021 n cm-2 (E > 1 MeV) or hydrogen-charged and heat-treated under stress to produce radial hydrides; the goal was to determine the microstructural and crystallographic characteristics of hydride precipitation. Morphologies, distributions, and habit planes of various types of hydrides were determined by stereo-TEM. In addition to the normal macroscopic hydrides commonly observed by optical microscopy, small “microscopic” hydrides are present in spent-fuel cladding in number densities at least a few orders of magnitude greater than that of macroscopic hydrides. The microscopic hydrides, observed to be stable at least up to 333°C, precipitate in association with